The AM05 density functional applied to solids

Author(s)
Ann E. Mattsson, Rickard Armiento, Joachim Paier, Georg Kresse, John M. Wills, Thomas R. Mattsson
Abstract

We show that the AM05 functional [Armiento and Mattsson, Phys. Rev. B72, 085108 (2005)] has the same excellent performance for solids as the hybrid density functionals tested in Paier et al. [J. Chem. Phys.124, 154709 (2006); 125, 249901 (2006)]. This confirms the original finding that AM05 performs exceptionally well for solids and surfaces. Hartree–Fock hybrid calculations are typically an order of magnitude slower than local or semilocal density functionals such as AM05, which is of a regular semilocal generalized gradient approximation form. The performance of AM05 is on average found to be superior to selecting the best of local density approximation and PBE for each solid. By comparing data from several different electronic-structure codes, we have determined that the numerical errors in this study are equal to or smaller than the corresponding experimental uncertainties.

Organisation(s)
Computational Materials Physics
External organisation(s)
Sandia National Laboratories, Universität Bayreuth, Center for Computational Materials Science, CMS, Los Alamos National Laboratory
Journal
Journal of Chemical Physics
Volume
128
No. of pages
11
ISSN
0021-9606
DOI
https://doi.org/10.1063/1.2835596
Publication date
2008
Peer reviewed
Yes
Austrian Fields of Science 2012
103009 Solid state physics, 103015 Condensed matter, 103025 Quantum mechanics, 103036 Theoretical physics
Portal url
https://ucrisportal.univie.ac.at/en/publications/the-am05-density-functional-applied-to-solids(e225cdb6-5d8a-4a59-8fe3-598b80cf2555).html