Oxygen-Stabilized Rh Adatoms: 0D Oxides on a Vicinal Surface
- Author(s)
- Florian Mittendorfer, Thomas Franz, J Klikovits, Michael Schmid, Lindsay R. Merte, Sameena Shah Zaman, Peter Varga, Rasmus Westerström, Andrea Resta, Jesper N. Andersen, Johan Gustafson, Edvin Lundgren
- Abstract
We have investigated the initial oxidation of the Rh(113) and Rh(223) vicinal surfaces by STM and ab initio simulations. Upon adsorption of small amounts of oxygen, the surface morphology is completely altered. Surprisingly, oxygen-stabilized Rh adatoms can be observed on the (113) facets, with oxide-like electronic properties. We present models of these "0D oxide" phases and discuss reasons for their stability.
- Organisation(s)
- Computational Materials Physics
- External organisation(s)
- Technische Universität Wien, Lund University
- Journal
- The Journal of Physical Chemistry Letters
- Volume
- 2
- Pages
- 2747-2751
- No. of pages
- 5
- DOI
- https://doi.org/10.1021/jz2011308
- Publication date
- 2011
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 103018 Materials physics
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/b5483235-5013-45f8-9029-50e088f1d870