Low-dimensional surface oxides in the oxidation of Rh particles

Author(s)
Florian Mittendorfer
Abstract

The oxidation of rhodium particles leads to the formation of low-dimensional nanostructures, namely ultrathin oxide films and stripes adsorbed on the metallic surface. These structures display unique electronic and structural properties, which have been studied in detail experimentally and theoretically in recent years. In this review, the state of research on low-dimensional surface oxides formed on Rh surfaces will be discussed with a special focus on the contributions derived from computational approaches. Several points elucidating the novel properties of the surface oxides will be addressed: (i) the structural relation between the surface oxides and their bulk counterparts, (ii) the electronic properties of the low-dimensional oxide films and (iii) potential catalytic and electronic applications of the surface oxides.

Organisation(s)
Computational Materials Physics
Journal
Journal of Physics: Condensed Matter
Volume
22
No. of pages
11
ISSN
0953-8984
DOI
https://doi.org/10.1088/0953-8984/22/39/393001
Publication date
2010
Peer reviewed
Yes
Austrian Fields of Science 2012
103018 Materials physics
Portal url
https://ucrisportal.univie.ac.at/en/publications/175cedb1-1c3d-4bc0-84e4-efbb9386aff4