Atomic-Scale View at the Segregation of Alkali Metals toward the KTaO3(001) Perovskite Surface
- Author(s)
- Aji Alexander, Michele Reticcioli, Llorenç Albons, Jesús Redondo, Marco Corrias, Igor Píš, Zhichang Wang, Viktor Johánek, Josef Mysliveček, Cesare Franchini, Dominik Wrana, Martin Setvin
- Abstract
Perovskites exhibit outstanding performance in applications such as photocatalysis, electrochemistry, or photovoltaics, yet their practical use is hindered by the instability of these materials under operating conditions, specifically caused by the segregation of alkali cations toward the surface. The problem arises from the bulk strain related to different cation sizes, as well as the inherent electrostatic instability of perovskite surfaces. Here, we focus on atomistic details of the surface-driven process of interlayer switching of alkali atoms at the inorganic perovskite surface. We show that the (001) surface of KTaO3 cleaved at room temperature contains equally populated TaO2 and KO terminations, while the uncompensated polarity of these terminations promotes diffusion of KO from the subsurface toward the topmost surface layer at temperatures as low as 200 °C. This effect is directly probed at the atomic scale by Atomic Force Microscopy and the chemical properties of the resulting surfaces are investigated by the adsorption of CO and H2O. The experiments indicate that KO segregation is associated with the formation of K and O vacancies in the near-surface region, which is further supported by depth-dependent X-ray Photoelectron Spectroscopy measurements and Density Functional Theory calculations. Our study shows that the KO segregation influences the surface reactivity both toward CO and water, which was probed at the atomic scale.
- Organisation(s)
- Computational Materials Physics
- External organisation(s)
- Charles University Prague, University of the Basque Country, Institute of Genetics and Biophysics "Adriano Buzzati-Traverso", CNR, Peking University, University of Bologna, Jagiellonian University in Krakow
- Journal
- ACS Applied Materials and Interfaces
- Volume
- 16
- Pages
- 70010-70019
- No. of pages
- 10
- ISSN
- 1944-8244
- DOI
- https://doi.org/10.1021/acsami.4c13795
- Publication date
- 12-2024
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 103018 Materials physics, 103020 Surface physics
- Keywords
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/109b5a6a-9da5-457e-b9dc-2c7e4f2f1e69